Numerical computation of critical properties and atomic basins from three-dimensional grid electron densities

نویسندگان

  • Claudine Katan
  • Philippe Rabiller
  • C. Lecomte
  • Maud Guezo
  • Vincent Oison
  • Mohamed Souhassou
  • C. Katan
  • P. Rabiller
  • M. Guezo
  • V. Oison
  • M. Souhassou
چکیده

InteGriTy is a software package that performs topological analysis following the AIM (atoms in molecules) approach on electron densities given on threedimensional grids. Tricubic interpolation is used to obtain the density, its gradient and the Hessian matrix at any required position. Critical points and integrated atomic properties have been derived from theoretical densities calculated for the compounds NaCl and TTF±2,5Cl2BQ (tetrathiafulvalene±2,5dichlorobenzoquinone), thus covering the different kinds of chemical bonds: ionic, covalent, hydrogen bonds and other intermolecular contacts.

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تاریخ انتشار 2017